全文获取类型
收费全文 | 909篇 |
免费 | 28篇 |
国内免费 | 73篇 |
专业分类
化学 | 360篇 |
晶体学 | 10篇 |
力学 | 23篇 |
综合类 | 2篇 |
数学 | 115篇 |
物理学 | 500篇 |
出版年
2024年 | 1篇 |
2023年 | 16篇 |
2022年 | 9篇 |
2021年 | 20篇 |
2020年 | 27篇 |
2019年 | 30篇 |
2018年 | 32篇 |
2017年 | 26篇 |
2016年 | 36篇 |
2015年 | 31篇 |
2014年 | 35篇 |
2013年 | 59篇 |
2012年 | 72篇 |
2011年 | 87篇 |
2010年 | 63篇 |
2009年 | 58篇 |
2008年 | 56篇 |
2007年 | 38篇 |
2006年 | 42篇 |
2005年 | 26篇 |
2004年 | 31篇 |
2003年 | 32篇 |
2002年 | 23篇 |
2001年 | 8篇 |
2000年 | 18篇 |
1999年 | 20篇 |
1998年 | 18篇 |
1997年 | 12篇 |
1996年 | 11篇 |
1995年 | 7篇 |
1994年 | 8篇 |
1993年 | 5篇 |
1992年 | 3篇 |
1991年 | 5篇 |
1990年 | 2篇 |
1989年 | 4篇 |
1988年 | 4篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 5篇 |
1984年 | 5篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1981年 | 10篇 |
1980年 | 1篇 |
1979年 | 5篇 |
1978年 | 1篇 |
1976年 | 1篇 |
1974年 | 1篇 |
排序方式: 共有1010条查询结果,搜索用时 921 毫秒
51.
Normal mode calculation of A-type zeolite was carried out with the potential energy functions obtained from the constraint method. Mass-weighted cartesian coordinates and the pseudo-lattice method were used. The assignments of IR absorption bands were made with the calculated normal modes, by using the calculated absorption intensities of the modes and the degrees of contribution of the internal coordinates to the modes. The force constants of internal coordinate motions within the framework were also calculated and are compared with the empirical values. 相似文献
52.
With a detailed analysis of the Bloch wave properties of one-dimensional infinite crystal, we find the exact analytical solution of the quantum confinement states in quantum well with infinite barrier. Based on the analytical solution, we calculate the complete electronic structure of quantum well with arbitrary geometries. The calculation results demonstrate that the transitions only occur between specific pairs of sub-bands. It also shows that the band edge state plays an insignificant role in the optical properties, although it is the most distinguishing feature of the quantum well. 相似文献
53.
Perdeuterated benzofluoranthenes have slightly shorter retention times than their equivalent unlabeled forms in a DB-5 capillary column. Under column overload conditions, perdeuterated benzofluoranthenes in moderate multifold excesses, which might be encountered in their use as internal standards and carriers for quantitative analysis, are seen to exhibit both normal and reverse solvent effects on their close eluting congeners. In some cases the effects may be used to advantage by knowledgeable analysts, but for the ignorant and unwary the effects can lead to serious errors in identification and quantification. 相似文献
54.
J. C. Gómez-Larrañaga F. González-Acuña Wolfgang Heil 《Mathematische Zeitschrift》2008,259(2):419-432
A closed topological n-manifold M
n
is of S
1-category 2 if it can be covered by two open subsets W
1,W
2 such that the inclusions W
i
→ M
n
factor homotopically through maps W
i
→ S
1 → M
n
. We show that the fundamental group of such an n-manifold is a cyclic group or a free product of two cyclic groups with nontrivial amalgamation. In particular, if n = 3, the fundamental group is cyclic.
相似文献
55.
Frederik Detobel Veronika Fekete Wim De Malsche Selm De Bruyne Han Gardeniers Gert Desmet 《Analytical and bioanalytical chemistry》2009,394(2):399-411
The present paper provides a detailed analysis of the analyte-wall adsorption effects in nanochannels, including a random
walk study of the analyte-wall collision frequency, and uses these insights to estimate wall desorption times from chromatographic
experiments in nanochannels. Using coumarin dye analytes and using a methanol/water mixture buffered at pH 3 in 120-nm deep
channels, the surface desorption times on naked fused-silica glass were found to be maximally of the order of 60 to 150 μs,
while they were found to be on the order of 100 to 500 μs on a hydrophobically coated wall. These nonzero adsorption and desorption
times lead to an additional band broadening when conducting chromatographic separations. Shear-driven flows, requiring a noncoated
moving wall and a stationary coated wall, intrinsically turn out to be more prone to this effect than pressure-driven or electro-driven
flows for example. The present study also shows that, interestingly, the number of analyte-wall collisions increases with
the inverse of the channel depth and not with its second power, as would be expected from the Einstein–Smoluchowski relationship
for molecular diffusion. 相似文献
56.
The paper provides a combinatorial method to decide when the space of local systems with nonvanishing first cohomology on the complement to an arrangement of lines in a complex projective plane has as an irreducible component a subgroup of positive dimension. Partial classification of arrangements having such a component of positive dimension and a comparison theorem for cohomology of Orlik–Solomon algebra and cohomology of local systems are given. The methods are based on Vinberg–Kac classification of generalized Cartan matrices and study of pencils of algebraic curves defined by mentioned positive dimensional components. 相似文献
57.
Perovskite solar cells have been studied extensively in the area of perovskite solar cells because they have a comparatively free hysteresis. Through fabrication of a perovskite solar cell based on a vanadium oxide buffer, this study clarified the mechanism of electron and hole transport in the laminated layer upon irradiation with light. The power conversion efficiency (PCE) of the Vanadium (Ⅳ) oxide (VO2) sputtering process device was approximately 13% and with the spin-coating process was 8.5%. To investigate the physicochemical origin of such PCE differences depending on the process type, comprehensive band alignment and band structure analyses of the actual cell stacks were performed using X-ray photoelectron spectroscopy depth measurements. Accordingly, it was found that the inconsistent valence band offset between the perovskite absorption layer and V2O5 layer as a function of the VO2 process type caused a difference in the hole transport, resulting in the difference in the efficiency. 相似文献
58.
基于光子晶体带边效应的表面增强拉曼基底 总被引:1,自引:0,他引:1
将光子晶体的带边效应与金纳米粒子的拉曼散射增强作用相结合,制备了一种新型光子晶体表面增强拉曼散射基底(PC-AuNPs),利用罗丹明B(RhB)作为报告分子,对所得基底性能进行检测.PC-AuNPs基底的制备包括3个步骤:在SiO2微球表面修饰氨基,再通过垂直沉降自组装得到蛋白石结构光子晶体(PC), 最后, 在光子晶体表面负载金纳米粒子(AuNPs).结果表明,光子晶体的带隙范围及AuNPs的负载量直接影响了PC-AuNPs基底的检测效果;以所得的PC-AuNPs基底测定RhB分子,其拉曼散射特征峰强度与浓度对数值呈现良好的线性关系,线性方程为I=1711lg[RhB(mol/L)]+15244,线性相关系数R2=0.9994,检出限为1×10-8 mol/L,表明此PC-AuNPs基底可用于目标物的定性及定量检测.本方法提高了传统拉曼散射光谱检测灵敏度,操作简单,具有良好的重现性,可为其它新型检测基底的制备提供. 相似文献
59.
Tatiana A. Shestimerova Alexander S. Mitiaev Dmitry I. Davliatshin Prof. Dr. Andrei V. Shevelkov 《无机化学与普通化学杂志》2010,636(11):1941-1946
Tetrasilver telluride sulfate was obtained as a black air‐stable polycrystalline powder; its structure was determined from X‐ray powder diffraction data. The new compound crystallizes in the cubic space group P213, with the unit cell parameter a = 8.6263(2) Å and Z = 4. The crystal structure of Ag4Te(SO4) is composed of a positively charged silver‐telluride three‐dimensional framework, in which the isolated tetrahedral SO42– anions are embedded. The framework features an irregular coordination for tellurium atoms with a coordination number of six and manifold Ag–Ag contacts ranging from 2.99 to 3.14 Å. The distortion of the SO42– anion as well as the interactions within the framework and between the framework and the SO42– anions are analyzed with the help of the structural data, vibrational spectra, and band structure calculations. 相似文献
60.
Dajiang Mei Zheshuai Lin Jiyong Yao Peizhen Fu 《Journal of solid state chemistry》2010,183(7):1640-2985
Two new bismuth sulfides KBiSiS4 and KBiGeS4 have been synthesized by means of the reactive flux method. They adopt the RbBiSiS4 structure type and crystallize in space group P21/c of the monoclinic system. The structure consists of (M=Si, Ge) layers separated by bicapped trigonal-prismatically coordinated K atoms. The M atom is tetrahedrally coordinated to four S atoms and the Bi atom is coordinated to a distorted monocapped trigonal prism of seven S atoms. The optical band gap of 2.25(2) eV for KBiSiS4 was deduced from the diffuse reflectance spectrum. From a band structure calculation, the optical absorption for KBiSiS4 originates from the layer. The Si 3p orbitals, Bi 6p orbitals, and S 3p orbitals are highly hybridized near the Fermi level. The orbitals of K have no contributions on both the upper of valence band and the bottom of conduction band. 相似文献